Bound and many-particle states in polariton Raman spectra of NH4Cl crystals

The properties of polariton Raman spectra for the internal vibration region of NH₄Cl crystal are discussed. These spectra have been recorded by means of a copper laser ( $\text{λ = 5105 and 5782}\text{A}\text{?}$) for sample temperature T=80 and 10°K.According to the theory a polariton singularities in the region of a polar bound state has been obtained. The two-particle bands have been studied and a very complicate structure inside of these bands has been revealed. Moreover, multiphonon singularities at polariton curves have been observed. The experimental polariton law has been compared to the theory and a conclusion has been made as to the necessity of a further development of the theory.