A vibrational spectroscopic study of TiCl3 |
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| Authors: | G.V. Fraser J.M. Chalmers V. Charlton M.E.A. Cudby |
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| Affiliation: | H.H. Wills Physics Laboratory, University of Bristol, Bristol, BS8 1TL, U.K.;Imperial Chemical Industries Ltd., Plastics Division, Welwyn Garden City, Herts., U.K. |
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| Abstract: | The α-, β- and γ-isomorphs of TiCl3 have been investigated using Raman spectroscopy. For this purpose a cell was designed specially for air sensitive compounds. The possibility of resonance effects in the Raman spectrum is discussed and some evidence is found for a pre-resonance Raman spectrum for the β-isomorph. Infra-red spectra are discussed in terms of the different types of lattice found in TiCl3. |
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