Prediction of the behaviour of organic pollutants using cloud point extraction |
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Authors: | Carabias-Martínez R Rodríguez-Gonzalo E Domínguez-Alvarez J García Pinto C Hernández-Méndez J |
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Institution: | Departamento de Química Analítica, Nutrición y Bromatología, Facultad de Química, Universidad de Salamanca, Plaza de la Merced s/n, 37008 Salamanca, Spain. rcm@usal.es |
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Abstract: | A preconcentration study based on the cloud point phenomenon was carried out for a set of triazine herbicides, three of them chloro-substituted and three of them methylthio-substituted. Concentration factors and recoveries were calculated as function of the percentage of the non-ionic surfactant Triton X-114 employed. From these values, obtained from a cloud point extraction (CPE) procedure, the distribution coefficient between the Triton X-114 micelles and water, Kc, prior to CPE was calculated for each triazine and related to the corresponding octanol-water partition coefficient, Kow. In order to confirm the results obtained with the triazine herbicides, two sets of data from chemically different organic pollutants--organophosporous and chlorophenols--obtained from the literature were assessed, concluding that they display a similar behaviour to that of the triazine herbicides. This can be used to predict the CPE behaviour of other organic pollutants from their octanol-water partition coefficients. The Kc values were compared with the analyte concentration ratio in the surfactant-rich phase and aqueous phase (Ksa) with a view to obtaining a link between the analyte behaviour prior to and after cloud point extraction procedures. |
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