Polarization Diagram of the Electrochemical Impedance of Second Order: A Theory that Accounts for the Diffusion of Reactants |
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| Authors: | V. V. Elkin V. Ya. Mishuk V. N. Alekseev B. M. Grafov |
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| Affiliation: | (1) Frumkin Institute of Electrochemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 117071, Russia |
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| Abstract: | With the aim of improving diagnostic possibilities of second-order impedance spectroscopy, a theory is put forward for a polarization diagram of a second-order impedance for reactions with charge transfer. The theory takes into account the diffusion of discharging particles in the absence of their specific adsorption. |
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