Mercury(II) oxide/tetrafluoroboric acid. An unusual behavior in the oxidation of alkenes. Synthesis of trans-cinnamylethers |
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| Authors: | José Barluenga Luisa Alonso-Cires Gregorio Asensio |
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| Institution: | Departamento de Química Orgánica. Facultad de Ciencias, Universidad de Oviedo. Oviedo, Spain |
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| Abstract: | The synthesis of -cinnamylethers by oxidation of allylbenzene is described. The reaction cannot be explained by formation of an allylic mercurial. A new type of mechanism in the oxidation of alkenes by mercury(II) salts is proposed. |
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