The mechanism of solvolysis of methyl perchlorate in hydroxylic solvents: calculation of the cavity terms |
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| Authors: | Michael H. Abraham Asadollah Nasehzadeh Joaquim J. Moura Ramos |
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| Affiliation: | Chemistry Department, University of Surrey, Guildford, Surrey, U.K.;Centro de Química-Física Molecular, Complexo Interdisciplinar, Institute Superior Tecnico, Av. Rovisco Pais, Lisboa, Portugal |
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| Abstract: | From standard Gibbs energies of transfer, corrected for cavity or nonelectrostatic effects, it is concluded that the solvolysis of methyl perchlorate takes place through a looser-than-usual SN2 transition state with a charge separation of about 0.52 units. |
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