The stability and nature of an SiC double bond. An ab initio mo study for 1,1-dimethylsilaethylene期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

The stability and nature of an SiC double bond. An ab initio mo study for 1,1-dimethylsilaethylene

Authors:	M. Hanamura S. Nagase K. Morokuma

Affiliation:	2. Institute for Molecular Science, Myodaiji, Okazaki 444, Japan;1. Faculty of Education, Yokohama National University, Hodogaya-ku, Yokohama 240, Japan

Abstract:	Several properties of Me₂SiCH₂(I) are calculated for the first time using the ab initio MO method. (I) is found to be substantially more stable than the isomers MeS?iCH₂Me(II) and Me₂HSiC?H(III), in contrast to the case of the parent compound (H₂SiCH₂). The geometry and vibrational frequencies are predicted.

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