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O-Silylated enolates in organic synthesis: α-Alkylation of carbonyl compounds by 1,3-dithienium fluoroborate. |
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| Authors: | Ian Paterson Lee G Price |
| Institution: | Department of Chemistry, University College London, 20 Gordon Street, London WC1H 0AJ, England |
| Abstract: | The O-silylated enolates of ketones, aldehydes, esters, and lactones can be regiospecifically alkylated by 1,5-dithienium fluoroborate to give the selectivity protected β-dicarbonyl compounds. |
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