Apparent anomalous behavior of polar substituents on the benzene ring in the regioselectivity of di-π-methane rearrangement of 5,6-benzo-2-azabicyclo[2.2.2]octadienones |
| |
| Authors: | Masayuki Kuzuya Eiichi Mano Masanao Ishikawa Takachiyo Okuda Harold Hart |
| |
| Institution: | Gifu College of Pharmacy, 5-6-1, Mitahora-Higashi, Gifu, 502, Japan;Department of Chemistry, Michigan State University, East Lansing, Michigan 48824, U.S.A. |
| |
| Abstract: | Polar substituent effects on the aromatic ring emerge in the regioselectivity of the di-π-methane rearrangement of the title compounds when they possess the structural feature of including the bridgehead carbon in a saturated ring; the importance of the environment at the bridgehead carbon is pointed out. |
| |
| Keywords: | |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
