1,2-dimagnesium derivatives of cyclopropane |
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Authors: | JWFL Seetz OS Akkerman F Bickelhaupt |
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Institution: | Vakgroep Organische Chemie, Vrije Universiteit De Boelelaan 1083, 1081 HV Amsterdam, The Netherlands |
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Abstract: | cis-1,2-Dibromomagnesiocyclopropane (cis-) was isolated from the reaction of both trans- and cis-1,2-dibromocyclopropane () with magnesium. The corresponding dialkylmagnesium species (), an oligomer of 2-magnesabicyclobutane, was obtained from cis- by precipitation in THF; it forms a soluble complex 8 with HgBr2. |
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