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1,2-dimagnesium derivatives of cyclopropane
Authors:JWFL Seetz  OS Akkerman  F Bickelhaupt
Institution:Vakgroep Organische Chemie, Vrije Universiteit De Boelelaan 1083, 1081 HV Amsterdam, The Netherlands
Abstract:cis-1,2-Dibromomagnesiocyclopropane (cis-4) was isolated from the reaction of both trans- and cis-1,2-dibromocyclopropane (1) with magnesium. The corresponding dialkylmagnesium species (7), an oligomer of 2-magnesabicyclobutane, was obtained from cis-4 by precipitation in THF; it forms a soluble complex 8 with HgBr2.
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