Regioselective 1,4-addition of nucleophiles to 1,3-diene monoepoxides catalyzed by palladium complex |
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Authors: | Jiro Tsuji Hideaki Kataoka Yuichi Kobayashi |
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Affiliation: | Tokyo Institute of Technology, Meguro, Tokyo 152, Japan |
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Abstract: | 1,3-Diene monoepoxides react with nucleophiles in the presence of palladium complex as a catalyst under neutral conditions to give 1,4-adducts selectively. The 1,4-adducts are allylic alcohols and there is a possibility of another nucleophilic attack. Ester of Monarch butterfly pheromone was prepared. |
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