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Organic sonochemistry. Ultrasound promoted coupling of chlorosilanes in the presence of lithium wire |
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| Authors: | Philip Boudjouk Byung Hee Han |
| Institution: | The Department of Chemistry North Dakota State University Fargo, ND 58105 USA |
| Abstract: | Triorganometal chlorides, R3MCl (R = alkyl, aryl, M = Si, Sn) are readily coupled to form bimetallics in 42–95% yields using Li wire and ultrasound. Dihalosilanes give good yields of cyclic polysilanes. |
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