Photolytic rearrangement of germanium azides. Evidence for transient germa-imines |
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| Authors: | Antoine Baceiredo Guy Bertrand Pierre Mazerolles |
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| Institution: | Laboratoire des Organometalliques, ERA 829, Université Paul Sabatier, 118 route de Narbonne, 31062 Toulouse cedex. France. |
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| Abstract: | Photolysis of germanium azides gives rise to transient germa-imines which have been quantitatively trapped by pinacol. Evidence for the formation of diphenylgermylene in the photolysis of hexaphenylcyclodigermazane is also reported. |
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