Fremy's salt oxidation of some isoquinoline alkaloids. Biogenetic considerations |
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| Authors: | Luis Castedo Alberto Puga José M Saá Rafael Suau |
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| Institution: | Departamento de Química Organica de la Facultad de Química e Institute de Productos Naturales Orgánicos (Sección Alcaloides) del C.S.I.C. Santiago de Compostela Spain |
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| Abstract: | Fremy's salt oxidation of benzyl isoquinoline and aporphine alkaloids to isoquinolones and oxoaporphines is described. Aminium radicals are suggested to account for the observed results. Their possible involvement in alkaloid biosynthesis is considered. |
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