| STUDY OF CARBONYLATION OF METHANOL TO ACETIC ACID AND ACETIC ANHYDRIDE OVER A BIDENTATE POLYMER BOUND CIS-DICARBONYLRHODIUM COMPLEX AS CATALYST |
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| 引用本文： | 王晓筠,柳忠阳,潘平来,袁国卿. STUDY OF CARBONYLATION OF METHANOL TO ACETIC ACID AND ACETIC ANHYDRIDE OVER A BIDENTATE POLYMER BOUND CIS-DICARBONYLRHODIUM COMPLEX AS CATALYST[J]. 高分子科学, 1996, 0(3): 233-239 |
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| 作者姓名： | 王晓筠 柳忠阳 潘平来 袁国卿 |
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| 作者单位： | Institute of Chemistry，Chinese Academy of Sciences，Beijing 100080，Institute of Chemistry，Chinese Academy of Sciences，Beijing 100080，Institute of Chemistry，Chinese Academy of Sciences，Beijing 100080，Institute of Chemistry，Chinese Academy of Sciences，Beijing 100080 |
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| 摘 要： | Copolymer of 2-vinylpyridine and vinylacetate coordinated with dicarbonylrhodiumused as a catalyst for carbonylation of methanol to acetic acid and anhydride has beenstudied. The structural characteristics of the copolymer ligand and complex, and the in-fluences of the reaction conditions on the carbonylation catalyzed by this polymer complexhave been investigated. In comparison with small molecule catalyst of Rh complex, thebidentate copolymer coordinated complex has better thermal stability. The reactionmechanism of the carbonylation reaction is also illustrated.
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| 收稿时间： | 1995-05-31 |
STUDY OF CARBONYLATION OF METHANOL TO ACETIC ACID AND ACETIC ANHYDRIDE OVER A BIDENTATE POLYMER BOUND CIS-DICARBONYLRHODIUM COMPLEX AS CATALYST* |
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| WANG Xiaojun,LIU Zhongyang,PAN Pinglai,YUAN Guoqing. STUDY OF CARBONYLATION OF METHANOL TO ACETIC ACID AND ACETIC ANHYDRIDE OVER A BIDENTATE POLYMER BOUND CIS-DICARBONYLRHODIUM COMPLEX AS CATALYST*[J]. Chinese Journal of Polymer Science, 1996, 0(3): 233-239 |
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| Authors: | WANG Xiaojun LIU Zhongyang PAN Pinglai YUAN Guoqing |
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| Affiliation: | Institute of Chemistry; Chinese Academy of Sciences; Bejing 100080 |
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| Abstract: | Copolymer of 2-vinylpyridine and vinylacetate coordinated with dicarbonylrhodiumused as a catalyst for carbonylation of methanol to acetic acid and anhydride has beenstudied. The structural characteristics of the copolymer ligand and complex, and the in-fluences of the reaction conditions on the carbonylation catalyzed by this polymer complexhave been investigated. In comparison with small molecule catalyst of Rh complex, thebidentate copolymer coordinated complex has better thermal stability. The reactionmechanism of the carbonylation reaction is also illustrated. |
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| Keywords: | Bidentate polymer cis-Dicarbonylrhodium complex Carbonylation of methanol Reaction mechanism |
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