Radiation effects on polymers—X: The grafting of acrylic acid on polyethylene in presence of a redox system using accelerated electrons |
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| Authors: | MI Aly K Singer NA Ghanem MA El-Azmirly |
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| Institution: | 1. National Centre for Radiation Research and Technology, Nasr City, Cairo, Egypt;2. Research Establishment Risø, Denmark;3. Laboratory of Polymers and Pigments, National Research Centre, Dokki, Cairo, Egypt |
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| Abstract: | Films of low-density polyethylene grafted with various amounts of polyacrylic acid were prepared by the direct irradiation method, using a 10 MeV linear electron accelerator. Aqueous solutions of acrylic acid were used with FeSO4 · 7H2O as a redox system. The best graft/homopolymer ratios were obtained at radiation doses between 2 and 3 Mrad, at acrylic acid concentrations of 40–60% and at FeSO4 · 7H2O concentrations of 0.25-0.5% by weight. The grafted films were tested for reverse osmosis properties. A membrane with 60% polyacrylic acid content gave 87% salt rejection and a water flux of 0.75 × 10?5 gm/cm2 per sec. |
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