A kinetic ESR study of the reaction of t-butylperoxy radicals with hexaphenylditin and hexaphenyldilead |
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| Authors: | JA HowardE Furimsky |
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| Institution: | Division of Chemistry, National Research Council of Canada, Ottawa, Ontario Canada |
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| Abstract: | Absolute rate constants for the reaction of t-butylperoxy radicals with hexaphenylditin and hexaphenyldilead have been found to fit the equations log (kp/M−1·s−1) = (5.5±0.15) − (3800±150)/Θ and log (kp/M−1·s−1) (9.5±0.3) − (6000±250)/Θ, where Θ = 2.303 RT cal mol−1, respectively. |
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