The fluorination of benzene over manganese trifluoride |
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Authors: | A.E. PedlerT.W. Rimmington R. StephensA.J. Uff |
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Affiliation: | Chemistry Department, The University, Edgbaston, Birmingham B15 2TT Gt. Britain |
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Abstract: | Flourination of benzene, in the vapour phase, over manganic fluoride at 300° has given undecafluorocylohexane (3.5%); 1H-, 3H- and 4H-nonafluorocyclohexene (3.3, 0.2 and 1.6%, respectively); 1H/2H- and 1H/4H-decafluorocyclohexane (1.1 and 6.2%, respectively); 1H,4H-hexafluorocyclohexa-1:4-diene (4.0%); 1H,2H- and 1H,4H-octafluorocyclohexene (0.04 and 15.8%, respectively); floruo- (3.9%), p-difluoro- and 1,2,4-trifluoro-benzene; 1H4H/2H, 1H/2H,4H- and 1H,2H/4H-nonafluorocyclohexane; and 1H,3H/4H-, 1H,4H/5H- and 1H, 2H,4H- (8.0%) heptafluorocyclohexene. |
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