| A Novel Synthesis of 3-O-Allyl-4, 5, 6-tri-O-benzyl-1-O-（p-methoxybenzyl）-D-myo-inositol |
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| 作者姓名： | ZhiZhouYUE YuanChaoLI |
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| 作者单位： | ShanghaiInstituteofMateriaMedica,ShanghaiInstitutesforBiologicalSciences,ChineseAcademyofSciences,ZhangjiangHi-TechPark,Shanghai201203 |
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| 摘 要： | Highly efficient synthesis of the entitled compound was achieved from a readily available myo-inositol derivative. The key step involved a desymmetrization with ( )-camphor dimethyl ketal to give two diastereomers. The two diastereomers could be used to synthesize the same compound by changing the orders to introduce the protective groups.
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| 关 键 词： | 合成方法 3-O-烯丙基-4 5 6-三-O-苯甲基-1-O-（P-甲氧基苯）-D-肌-纤维醇 肌糖 新陈代谢 细胞 |
A Novel Synthesis of 3-O-Allyl-4, 5, 6-tri-O-benzyl-1-O-(p-methoxybenzyl)-D-myo-inositol |
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| ZhiZhouYUE YuanChaoLI.A Novel Synthesis of 3-O-Allyl-4, 5, 6-tri-O-benzyl-1-O-(p-methoxybenzyl)-D-myo-inositol[J].Chinese Chemical Letters,2005,16(2):171-174. |
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| Authors: | Zhi Zhou YUE Yuan Chao LI |
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| Institution: | Zhi Zhou YUE,Yuan Chao LI* Shanghai Institute of Materia Medica,Shanghai Institutes for Biological Sciences,Chinese Academy of Sciences,Zhangjiang Hi-Tech Park,Shanghai 201203 |
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| Abstract: | Highly efficient synthesis of the entitled compound was achieved from a readily availablemyo-inositol derivative. The key step involved a desymmetrization with (+)-camphor dimethylketal to give two diastereomers. The two diastereomers could be used to synthesize the samecompound by changing the orders to introduce the protective groups. |
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| Keywords: | nositol (+)-camphor dimethyl ketal desymmetrization |
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