| 固体碱D301树脂在杂环卤代芳烃Heck反应中的应用 |
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| 引用本文： | 吴香梅,裴文. 固体碱D301树脂在杂环卤代芳烃Heck反应中的应用[J]. 有机化学, 2009, 29(4): 584-588 |
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| 作者姓名： | 吴香梅 裴文 |
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| 作者单位： | 浙江工业大学化学工程与材料学院,杭州,310014 |
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| 基金项目： | 国家自然科学基金，浙江省自然科学基金 |
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| 摘 要： | 利用D301树脂作为碱性试剂, 在无膦配体, 低用量Pd(OAc)2催化下进行了杂环卤代芳烃与烯烃的Heck芳基化反应研究, 实验结果表明D301树脂作为固体碱不仅可使反应获得满意的收率, 而且具有良好的重复使用性能.
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| 关 键 词： | Heck反应 D301树脂 杂环卤代芳烃 |
| 收稿时间： | 2008-05-14 |
| 修稿时间： | 2008-04-17 |
D301 Resin as a Solid Base for Phosphine-Free Heck Reaction with Heteroaryl Halides |
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| Wu Xiangmei,Pei Wen. D301 Resin as a Solid Base for Phosphine-Free Heck Reaction with Heteroaryl Halides[J]. Chinese Journal of Organic Chemistry, 2009, 29(4): 584-588 |
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| Authors: | Wu Xiangmei Pei Wen |
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| Affiliation: | (College of Chemical Engineering and Materials, Zhejiang University of Technology, Hangzhou 310014) |
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| Abstract: | D301 resin has been used as a base in the Heck reaction of heteroaryl halides with olefins in the absence of phosphine ligand at a low Pd concentration. It was found that D301 resin was an efficient and reusable base, which could be regenerated and recycled in the reaction. The olefination of heteroaryl halides prepared the corresponding products in good yields. |
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| Keywords: | Heck reaction D301 resin heteroaryl halide |
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