Highly efficient photoreduction of water using energy transfer |
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Authors: | Oddvar Johansen Albert W.-H. Mau Wolfgang H.F. Sasse |
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Affiliation: | Division of Applied Organic Chemistry, CSIRO, Box 4331, Melbourne 3001, Australia |
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Abstract: | The photochemistry of the system water-tris(2,2′-bipyridine)ruthenium(II) dication—9-anthracenecarboxylate anion—methylviologen—ethylenediaminetetraacetic acid—platinum has been studied. Efficient triplet energy transfer from the excited ruthenium complex to the anthracene derivative leads to the formation of hydrogen in quantum yields up to 0.85. |
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