Eldor spin echoes and slow motions |
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| Authors: | Joseph P Hornak Jack H Freed |
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| Institution: | Baker Laboratory of Chemistry, Cornell University, Ithaca, New York 14853, USA |
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| Abstract: | It is shown how an ELDOR technique based upon spin echoes and rapid stepping of the magnetic field may be employed to measure rotational correlation times, τR for very slow motions. Experiments on PD-Tempone in 85% glycerol/ D2O at low temperatures led to τR values of 10?4 to 10?5 s obtained with a simple analysis of the data. |
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