Time-dependent mass spectra and breakdown graphs. The kinetic shift in aniline |
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Authors: | C. Lifshitz P. Gotchiguian R. Roller |
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Affiliation: | Department of Physical Chemistry. The Hebrew University of Jerusalem, Jerusalem 91904, Israel |
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Abstract: | Time-resolved appearance energies and metastable peak shapes were determined by trapped-ion mass spectrometry (TIMS) for the unimolecular dissociation of aniline cations. The long-time (milliseconds) appearance energy limit, AE(C5H+6) = 11.26 = 0.2 eV. suggests the formation at threshold energies of the cyclopentadienyl cation with neutral hydrogen isocyanide. HNC. |
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