Time-dependent mass spectra and breakdown graphs. The kinetic shift in aniline |
| |
| Authors: | C Lifshitz P Gotchiguian R Roller |
| |
| Institution: | Department of Physical Chemistry. The Hebrew University of Jerusalem, Jerusalem 91904, Israel |
| |
| Abstract: | Time-resolved appearance energies and metastable peak shapes were determined by trapped-ion mass spectrometry (TIMS) for the unimolecular dissociation of aniline cations. The long-time (milliseconds) appearance energy limit, AE(C5H+6) = 11.26 = 0.2 eV. suggests the formation at threshold energies of the cyclopentadienyl cation with neutral hydrogen isocyanide. HNC. |
| |
| Keywords: | |
| 本文献已被 ScienceDirect 等数据库收录！ |
