Dielectric study of dipolar association in dilute solutions of nitrobenzene in benzene |
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Authors: | Maria Dutkiewicz Bolesław Szurkowski Tadeusz Hilczer |
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Institution: | Institute of Physics, A. Miekiewicz University, 60-780 Poznań, Poland |
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Abstract: | The correlation factors Rp and Rs are determined for the dielectric polarization and the non-linear dielectric effect in dilute solutions of nitrobenzene in benzene. Assuming dipole association of the nitrobenzene molecules to be restricted to dimerization, we determined the concentration x2 of dimers, their dipole moment μdim, and the equilibrium constant Kx and Gibbs energy ΔG of the dimerization process. |
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