Quantum-chemical approach to the elementary steps of plasma etching |
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Authors: | Dieter K Fricke Hans Müller Ch Opitz |
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Institution: | Sektion Chemie der Friedrich-Schiller-Universität Jena, Steiger 3, Hous 3, DDR-6900 Jena, DDR |
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Abstract: | We derive for the first time a mechanism of reactive plasma etching in the system Si/F by the quantum-chemical approach. SiF2-like species at the surface play an important role. SiF3 surface complexes also occur. The final etching product SiF4 is formed with high probability in the gas phase. |
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