Reply to comment on an unexpected symmetry of the Coulomb potential in the Debye-Smoluchowski equation |
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| Authors: | P. Clifford N.J.B. Green M.J. Pilling |
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| Affiliation: | Mathematical Institute, St. Giles, Oxford OX1 3LB, UK;Physical Chemistry Laboratory, South Parks Road, Oxford OX1 3QZ, UK |
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| Abstract: | A properly modified inner boundary condition is used in an analysis of the conditional reaction probability, φ*R (r0, t), using the Debye-Smoluchowski equation. It is shown that the Coulomb potential modifies the reaction velocity at the boundary by the addition of a drift term. φ*R (r0, t) is identifical for attractive and repulsive cases if a constant term is added to the boundary velocity for the attractive potential. |
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