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Vibrational excitation of OH(X2Π) produced in the reaction of O(1D) with H2 |
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| Authors: | J.E. Butler R.Glen MacDonald D.J. Donaldson J.J. Sloan |
| Affiliation: | Naval Research Laboratory, Washington, D.C. 20375, USA;Physical Chemistry Branch, Atomic Energy of Canada Ltd., Chalk River, Canada KOJ IJO;Division of Chemistry, National Research Council of Canada, Ottawa, Canada KIA OR6 |
| Abstract: | A lower limit to the OH(X2Π) vibrational excitation produced by the reaction O(1D) + H2 has been observed using a low-pressure infrared chemiluminescence apparatus. The O(1D) was generated by laser photolysis of O3. The measured OH(v') vibrational distribution is inverted; it peaks at v' = 2. |
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