Molecular complexes of cyclopropane with hydrogen halides and water studied by matrix-isolation vibrational spectroscopy |
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| Authors: | A.J. Barnes S.L. Paulson |
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| Affiliation: | Department Chemistry and Applied Chemistry, University of Salford, Salford M5 4WT, UK |
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| Abstract: | Infrared spectra of cyclopropane-hydrogen halide and cyclopropane-water complexes show similar perturbations of the cyclopropane modes, suggesting that all have the proton donor “hydrogen-bonded” to the ring edge. The spectrum of the cyclopropane-water complex is consistent with water forming a bifurcated hydrogen bond to the ring. |
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