| 功能性离子液体支载液相有机合成研究进展 |
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| 引用本文： | 胡燚,李恒,黄和,韦萍.功能性离子液体支载液相有机合成研究进展[J].有机化学,2007,27(10):1188-1194. |
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| 作者姓名： | 胡燚 李恒 黄和 韦萍 |
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| 作者单位： | 南京工业大学制药与生命科学学院,南京,210009 |
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| 基金项目： | 国家重点基础研究发展规划(No.2003CB716004)，国家自然科学基金(No.20336010)资助项目. |
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| 摘 要： | 阐述了功能性离子液体支载液相有机合成的概念、特点及其在小分子杂环化合物、多肽、寡糖合成等有机反应中的应用, 以及功能性离子液体支载的催化剂和试剂在液相有机合成中的应用. 研究表明功能性离子液体作为一种新型的高负载量的可溶性载体可以广泛应用于液相有机合成中, 有效地促进了反应的进行, 简化了分离手段, 显著地提高了反应的选择性和收率.
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| 关 键 词： | 离子液体 液相有机合成 载体 组合化学 |
| 收稿时间： | 2006-11-29 |
| 修稿时间： | 2006-11-29 |
Advance in Liquid-Phase Organic Synthesis Using Functional Ionic Liquid as Supports |
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| HU Yi,LI Heng,HUANG He,WEI Ping.Advance in Liquid-Phase Organic Synthesis Using Functional Ionic Liquid as Supports[J].Chinese Journal of Organic Chemistry,2007,27(10):1188-1194. |
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| Authors: | HU Yi LI Heng HUANG He WEI Ping |
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| Institution: | College of Life Science and Pharmaceutical Engineering, Nanfing University of Technology, Nanjing 210009 |
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| Abstract: | This paper focuses on the concept and features of functional ionic liquid supported liquid-phase organic synthesis, and its application to the synthesis of small molecular heterocycles, peptides, oligosaccharides. The application of functional ionic liquid supported catalysts and reagents to liquid-phase organic synthesis is also described. As demonstrated in this paper, the functional ionic liquid could be used widely as novel soluble supports with high loading capacity in liquid-phase organic synthesis promoting the reactions effectively, simplifying the isolation operation, giving higher yields and selectivity as well. |
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| Keywords: | ionic liquid liquid-phase organic synthesis support combinatory chemistry |
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