Phosphoesterase activity of polyoxomolybdates: diffusion ordered NMR spectroscopy as a tool for obtaining insights into the reactivity of polyoxometalate clusters |
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| Authors: | Lokeren Luk Van Cartuyvels Els Absillis Gregory Willem Rudolph Parac-Vogt Tatjana N |
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| Affiliation: | Vrije Universiteit Brussels, High Resolution NMR centrum, Pleinlaan 2, B-1050 Brussels, Belgium. |
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| Abstract: | Diffusion ordered NMR spectroscopy (DOSY NMR) is shown to be an excellent tool for observing reactive transients in the hydrolysis of the phosphatase model substrate (p-nitrophenyl)phosphate (NPP) promoted by polyoxomolybdate. |
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