| Syntheses and Crystal Structures of Two Mononuclear Tin（IV） Complexes Derivedfrom Sn（edt）2 （edt = Ethane-1,2-dithiolate） |
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| 引用本文： | 张建军,吴立明,胡胜民,王龙胜,杜文新,吴新涛. Syntheses and Crystal Structures of Two Mononuclear Tin（IV） Complexes Derivedfrom Sn（edt）2 （edt = Ethane-1,2-dithiolate）[J]. 结构化学, 2004, 23(1): 29-32 |
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| 作者姓名： | 张建军 吴立明 胡胜民 王龙胜 杜文新 吴新涛 |
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| 作者单位： | State Key Laboratory of Structural Chemistry，Fujian Institute of Research on the Structure of Matter，The Chinese Academy of Sciences，Fuzhou，Fujian 350002，China |
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| 基金项目： | This research was financially supported by the grants from the State Key Laboratory of Structural Chemistry，the National Science and Technology of China (001CB1089)，the Chinese Academy of Sciences (CAS)，the National Science Foundation of China (20 |
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| 摘 要： | 1INTRODUCTIONRecentlythedesignandsynthesisoftinsulfide-basedsolidstatematerialshasreceivedmuchattentionowningtotheirinterestingoptical,catalyticandelectricalpropertiesfordeviceappli-cations[1].Becauseoftheversatilecoordinationcharacteristicsoftinandsulfur…
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| 关 键 词： | 单核配合物 锡（IV） 衍生物 有机化合物 乙烷-1，2-二硫醇 合成 晶体结构 Sn（edt）2 |
Syntheses and Crystal Structures of Two Mononuclear Tin(IV) Complexes Derived from Sn(edt)2 (edt = Ethane-1,2-dithiolate) |
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| Affiliation: | State Key Laboratory of Structural Chemistry,Fujian Institute of Research on the Structure of Matter,The Chinese Academy of Sciences,Fuzhou,Fujian 350002,China;State Key Laboratory of Structural Chemistry,Fujian Institute of Research on the Structure of Matter,The Chinese Academy of Sciences,Fuzhou,Fujian 350002,China;State Key Laboratory of Structural Chemistry,Fujian Institute of Research on the Structure of Matter,The Chinese Academy of Sciences,Fuzhou,Fujian 350002,China;State Key Laboratory of Structural Chemistry,Fujian Institute of Research on the Structure of Matter,The Chinese Academy of Sciences,Fuzhou,Fujian 350002,China;State Key Laboratory of Structural Chemistry,Fujian Institute of Research on the Structure of Matter,The Chinese Academy of Sciences,Fuzhou,Fujian 350002,China;State Key Laboratory of Structural Chemistry,Fujian Institute of Research on the Structure of Matter,The Chinese Academy of Sciences,Fuzhou,Fujian 350002,China |
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| Abstract: | Two mononuclear tin(IV) complexes, [Sn(pda)2(edt)2] (pda = o-phenylenediamine) (C16H24N4S4Sn, Mr = 519.32) 1 and [Sn(eda)(edt)2] (eda = ethylenediamine) (C6H16N2S4Sn, Mr = 363.14) 2 were synthesized and characterized by X-ray structure analysis. 1 belongs to trigonal, space group P-3c1 with a = b = 20.0280(6), c = 8.7679(5) ? V = 3045.8(2) ?, Z = 6, Dc = 1.699 g/cm3, m = 1.677 mm-1, F(000) = 1572, the final R = 0.0418 and wR = 0.1019 for 1805 independent reflections. 2 crystallizes in monoclinic, space group P21/c with a = 10.911(3), b = 9.783(2), c = 11.831(3) ? b = 100.28(2), V = 1242.6(6) ?, Z = 4, Dc = 1.941 g/cm3, m = 2.690 mm-1, F(000) = 720, the final R = 0.0280 and wR = 0.0627 for 2166 independent reflections. Both Sn4+ ions in these two complexes are six-coordinated with a slightly distorted octahedral configu- ration. |
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| Keywords: | crystal structure tin(IV) ethane-1 2-dithiolato |
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