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Zeolite-encapsulated Cr(III), Fe(III), Ni(II), Zn(II) and Bi(III) salpn complexes as catalysts for the decomposition of H2O2 and oxidation of phenol
Authors:M R Maurya  S J J Titinchi  S Chand  I M Mishra
Institution:

a Department of Chemistry, Indian Institute of Technology, Roorkee 247667, India

b Department of Chemical Engineering, Indian Institute of Technology, Roorkee 247667, India

Abstract:Cr(III), Fe(III), Bi(III), Ni(II) and Zn(II) complexes of N,N′-bis(salicylidene)propane-1,3-diamine (H2salpn) encapsulated in Y-zeolite were prepared by flexible ligand method. These complexes were characterized by chemical and thermal analyses, FT-IR and electronic spectral studies and their XRD pattern. The encapsulated materials are active catalysts for the decomposition of hydrogen peroxide and for the oxidation of phenol using H2O2 as oxidant with good selectivity.
Keywords:Encapsulation  Y-zeolite  Spectroscopy  Oxidation of phenol  H2O2 decomposition
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