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Investigation of new fluxes for the single-crystal growth of stoichiometric lithium niobate
Authors:G Dravecz  B Shackmann  M Cochez  M Ferriol
Institution:(1) Laboratoire M.O.P.S., U.M.R. C.N.R.S. 7132, IUT de Moselle Est, Département Chimie, B.P. 80105, rue Victor Demange, 57500 Saint-Avold, France;(2) Research Institute for Solid State Physics and Optics, Crystal Physics Laboratory, Hungarian Academy of Sciences, 1121 Budapest, Konkoly Thege M. út 29–33, P.O.B. 49, Budapest, Hungary, 1525
Abstract:Thermoanalytical and crystal growth investigations of the ternary system Cs2O-Li2O-Nb2O5 are presented in order to grow stoichiometric LiNbO3 (LN) crystals. Part of the phase diagram is determined and subsolidus phases are identified at room temperature by X-ray powder diffraction. Among the constituent phases, a new tetragonal cesium lithium niobate phase is assessed. From the Cs2O-Li2O-Nb2O5 system, good quality quasi-stoichiometric LN crystals can be grown.
Keywords:crystal growth  flux  phase diagram  stoichiometric lithium niobate
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