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聚硅酸硫酸铁/壳聚糖复合絮凝剂的制备及其在废水处理中的应用
引用本文:王九思,何兆照,郭立新,文卓琼,杨玉华. 聚硅酸硫酸铁/壳聚糖复合絮凝剂的制备及其在废水处理中的应用[J]. 应用化学, 2011, 28(1): 27-32. DOI: 10.3724/SP.J.1095.2011.00215
作者姓名:王九思  何兆照  郭立新  文卓琼  杨玉华
作者单位:(兰州交通大学化学与生物工程学院 兰州 730070)
基金项目:甘肃省自然科学基金B类项目
摘    要:制备了无机高分子复合絮凝剂聚硅酸硫酸铁(PFSS)和助凝剂壳聚糖(CTS),考察了影响合成及絮凝剂应用的因素,探讨了其组成、投加量以及pH值对城市废水絮凝效果的影响,通过对模拟废水和城市废水絮凝试验,得出最佳的合成和应用条件:n(Fe)∶n(Si)=1∶1,PFSS的碱化度为1.5,聚合硫酸铁(PFS)的pH=2,聚硅酸(PS)的活化时间为1.5 h;n(PFSS)∶n(CTS)=5∶1,投加量为(20+4) mg/L,pH值的范围为6~9,沉降时间为15 min。 复合絮凝剂(PFSS-CTS)在最佳条件下浊度、色度、COD的去除率分别达到95.04%、91.26%和83.45%。

关 键 词:聚硅酸硫酸铁  壳聚糖  复合絮凝剂  废水处理  
收稿时间:2010-04-13
修稿时间:2010-07-06

Preparation of Composite Flocculant (Polyferric Silicate Sulfate and Chitosan) and Its Application in Wastewater Treatment
WANG Jiusi,HE Zhaozhao,GUO Lixin,WEN Zhuoqiong,YANG Yuhua. Preparation of Composite Flocculant (Polyferric Silicate Sulfate and Chitosan) and Its Application in Wastewater Treatment[J]. Chinese Journal of Applied Chemistry, 2011, 28(1): 27-32. DOI: 10.3724/SP.J.1095.2011.00215
Authors:WANG Jiusi  HE Zhaozhao  GUO Lixin  WEN Zhuoqiong  YANG Yuhua
Affiliation:(School of Chemical and Biological Engineering,Lanzhou Jiaotong University,Lanzhou 730070)
Abstract:An inorganic polymeric composite flocculant polyferric silicate sulfate(PFSS) and assistant flocculant chitosan(CTS) have been prepared.Factors that influence the synthesis and applications of the flocculants have been investigated.The composition,dosage and pH value have been discussed in terms of treating the municipal wastewater.The optimal conditions of synthesis and application have been achieved by the flocculation test of simulated wastewater and municipal wastewater.The results show that the molar r...
Keywords:PFSS  chitosan  composite flocculants  wastewater treatment  
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