Preparation of tritylated 1,2-0-(1-methoxycarbonyl)ethylidene derivatives of carbohydrates and their conversion into tritylated 1,2-0-(1-cyano)ethylidene derivatives |
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Authors: | N. é. Bairamova L. V. Bakinovskii N. K. Kochetkov |
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Affiliation: | (1) N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow |
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Abstract: | Conclusion Tritylation of 1,2-0-1-(methoxycarbonyl)ethylidene derivative of carbohydrates followed by ammonolysis of the methoxycarbonyl group and dehydration was proposed as an alternative method for the preparation of tritylated 1,2-0-1-(cyano)ethylidene derivatives for use as monomers for polycondensation.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1126–1131, May, 1987. |
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