Structural features of light-sensitive crystals of N′-[2-nitrofurfuryl-5-vinyl]benzhydrazide and [N′-furfurylidene)]benzhydrazide |
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| Authors: | S M Aldoshin I I Chuev L O Atovmyan O A Kozina V S Nedzvetskii |
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| Institution: | (1) N. N. Semenov Institute of Chemical Physics, Academy of Sciences of the USSR, Chernogolovka Branch, USSR |
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| Abstract: | An x-ray structural study found that N -2-nitrofurfuryl-5-vinyl]benzhydrazide and N-(furfurylidene)]benzhydrazide do not form crystal hydrates although they have polar syn-conformations. Molecules in the crystal are joined by linear chains of intermolecular H-bonds C=O...H-N. The light-sensitivity of the crystals increases with decreasing packing density.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1556–1562, July, 1990. |
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