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A tightly coupled bis(zinc(II) phthalocyanine)-perylenediimide ensemble to yield long-lived radical ion pair states
Authors:Jiménez Angel J  Spänig Fabian  Rodríguez-Morgade M Salomé  Ohkubo Kei  Fukuzumi Shunichi  Guldi Dirk M  Torres Tomás
Institution:Departamento de Química OrgAnica, Universidad Autónoma de Madrid, Campus de Cantoblanco, 28049-Madrid, Spain.
Abstract:A conjugated donor-acceptor array composed of two phthalocyanines connected to the bay region of a perylenediimide is assembled by using palladium chemistry. Excitation of the phthalocyanine produces a nanosecond lived charge-separated state.
Keywords:
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