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Communication: Bubbles, crystals, and laser-induced nucleation
Authors:Knott Brandon C  LaRue Jerry L  Wodtke Alec M  Doherty Michael F  Peters Baron
Institution:Department of Chemical Engineering, University of California, Santa Barbara, California 93106-5080, USA.
Abstract:Short intense laser pulses of visible and infrared light can dramatically accelerate crystal nucleation from transparent solutions; previous studies invoke mechanisms that are only applicable for nucleation of ordered phases or high dielectric phases. However, we show that similar laser pulses induce CO(2) bubble nucleation in carbonated water. Additionally, in water that is cosupersaturated with argon and glycine, argon bubbles escaping from the water can induce crystal nucleation without a laser. Our findings suggest a possible link between laser-induced nucleation of bubbles and crystals.
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