Copper-catalyzed direct amination of electron-deficient arenes with hydroxylamines |
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Authors: | Matsuda Naoki Hirano Koji Satoh Tetsuya Miura Masahiro |
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Affiliation: | Department of Applied Chemistry, Faculty of Engineering, Osaka University, Suita, Osaka, Japan. |
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Abstract: | The C-H amination of electron-deficient arenes such as polyfluoroarenes and azole compounds with O-acylated hydroxylamines effectively proceeds in the presence of a copper catalyst even at room temperature to provide the corresponding anilines and aminoazoles in good yields. |
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