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Copper-catalyzed direct amination of electron-deficient arenes with hydroxylamines
Authors:Matsuda Naoki  Hirano Koji  Satoh Tetsuya  Miura Masahiro
Affiliation:Department of Applied Chemistry, Faculty of Engineering, Osaka University, Suita, Osaka, Japan.
Abstract:The C-H amination of electron-deficient arenes such as polyfluoroarenes and azole compounds with O-acylated hydroxylamines effectively proceeds in the presence of a copper catalyst even at room temperature to provide the corresponding anilines and aminoazoles in good yields.
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