| Mn(Ⅲ)-mediated radical reaction of 2-isocyano-6-alkenyl(alkynyl)benzonitriles with arylboronic acids:Synthesis of pyrroloisoquinoline derivatives |
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| 作者姓名： | Pei Xu Yi-Ming Zhu Xin-Yu Liu Xiao-Zhou Zhou Shun-Yi Wang Shun-Jun Ji |
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| 作者单位： | Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Materials Science & Collaborative Innovation Center of Suzhou Nano Science and Technology, Soochow University, Suzhou 215123, China |
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| 基金项目： | We gratefully acknowledge the National Natural Science Foundation of China (Nos. 21971174, 21772137, 21542015 and 21672157), PAPD, the Project of Scientific and Technologic Infrastructure of Suzhou (No. SZS201708), the Major Basic Research Project of the Natural Science Foundation of the Jiangsu Higher Education Institutions (No. 16KJA150002), Soochow University for financial support. |
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| 摘 要： | A Mn(Ⅲ) mediated radical reaction of new designed multi-functionalized 2-isocyano-6-alkenyl(alkynyl)benzonitriles with arylboronic acids has been developed.This reaction provides a method for the synthesis of pyrroloisoquinoline derivatives through the formation of two C-C bonds and one C-N bond via radical cascade cyclization in one step.
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| 关 键 词： | 2-Isocyano-6-alkenyl(alkynyl)benzonitriles Arylboronic acids Pyrroloisoquinoline derivatives Radical reaction |
| 收稿时间： | 2020-01-19 |
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