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A biomass based photonic crystal made of "konjac tofu"
作者姓名:Wenxin Zhang  Min Xue  Kenneth J. Shea  Lili Qiu  Zhibin Xu  Jing Fan  Dan Yan  Zihui Meng
作者单位:School of Chemistry and Chemical Engineering, Beijing Institute of Technology, Beijing 10081, China;; Department of Chemistry, University of California Irvine, CA 92697, United States
基金项目:This research was supported by the National Natural Science Foundation of China (Nos. 21874009, 21804009).
摘    要:Konjac tofu is a traditional Chinese food whose main ingredient is the water-soluble polysaccharide from konjac tubers-konjac glucomannan(KGM).Herein we report an interpenetrating double network polymeric film by crosslinking KGM and polyvinyl alcohol(PVA) with glutaraldehyde under acidic conditions.PVA was introduced into the hydrogel system as a hard skeleton,which not only maintained the biocompatibility of KGM,but also gave the hydrogel superior mechanical properties and solvent resistance.Implanting a colloidal array inside the above film,we obtained a new type of biomass based photonic crystal that is sensitive to a variety of physical and chemical stimulus,especially for methanol.This photonic crystal responds to metha nol and methanol vapo r,and has the ability to detect methanol in gasoline,which has a good application prospect.

关 键 词:Photonic  crystals  Konjac  glucomannan  HYDROGEL  Interpenetrating  double  network  Sensor

A biomass based photonic crystal made of “konjac tofu”
Wenxin Zhang,Min Xue,Kenneth J. Shea,Lili Qiu,Zhibin Xu,Jing Fan,Dan Yan,Zihui Meng.A biomass based photonic crystal made of "konjac tofu"[J].Chinese Chemical Letters,2021,32(1):587-590.
Authors:Wenxin Zhang  Min Xue  Kenneth J Shea  Lili Qiu  Zhibin Xu  Jing Fan  Dan Yan  Zihui Meng
Institution:School of Chemistry and Chemical Engineering, Beijing Institute of Technology, Beijing 10081, China; Department of Chemistry, University of California Irvine, CA 92697, United States
Abstract:Konjac tofu is a traditional Chinese food whose main ingredient is the water-soluble polysaccharide from konjac tubers-konjac glucomannan (KGM). Herein we report an interpenetrating double network polymeric film by crosslinking KGM and polyvinyl alcohol (PVA) with glutaraldehyde under acidic conditions. PVA was introduced into the hydrogel system as a hard skeleton, which not only maintained the biocompatibility of KGM, but also gave the hydrogel superior mechanical properties and solvent resistance. Implanting a colloidal array inside the above film, we obtained a new type of biomass based photonic crystal that is sensitive to a variety of physical and chemical stimulus, especially for methanol. This photonic crystal responds to methanol and methanol vapor, and has the ability to detect methanol in gasoline, which has a good application prospect.
Keywords:Photonic crystals  Konjac glucomannan  Hydrogel  Interpenetrating double network  Sensor  
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