Achieving room temperature phosphorescence from organic small molecules on amino acid skeleton |
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| Authors: | Zifei Wang Teng Li Bingbing Ding Xiang Ma |
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| Affiliation: | Key Laboratory for Advanced Materials and Feringa Nobel Prize Scientist Joint Research Center, School of Chemistry and Molecular Engineering, East China University of Science and Technology, Shanghai 200237, China |
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| Abstract: | Room temperature phosphorescence (RTP) generated by small molecules has attracted great attention due to their unique potentials for biosensor, bioimaging and security protection. While, the design of RTP materials is extremely challenging for organic small molecules in non-crystalline solid state. Herein, we report a new strategy for achieving non-crystalline organic small molecules with RTP emission by modifying different phosphors onto diphenylalanine or phenylalanine derivatives. Benefiting from the skeletal structure of the amino acid derivatives, there are intermolecular hydrogen bond formation and rigidification effect, thereby minimizing the intermolecular motions and enhancing their RTP performance |
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| Keywords: | Room temperature phosphorescence Amino acid Phenylalanine Diphenylalanine |
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