| Layer Zirconogermanate——(H_2DETA)[ZrGe_3O_8F_2] Showing Odd 3MR and 7MR |
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| 作者单位： | [1]School of Chemical Engineering, Changchun University of Technology, Changchun 130012, P. R. China [2]College of Chemistry and Molecular Engineering, Qingdao University of Science ＆ Technology, Qingdao 266042, P. R. China |
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| 基金项目： | Supported by the Scientific Research Foundation for the Returned Overseas Chinese Scholars(No.20071108); the National Natural Science Foundation of China(No.20701023) |
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| 摘 要： | A layered zirconogermanate,(H2DETA)ZrGe3O8F2](1),was hydro(solvo)thermally synthesized with diethylenetriamine(DETA) as template,and structurally determined by X-ray single-crystal diffraction. Compound 1 crystallized in the monoclinic space group P21/c with data of unit cell:a=0.7644(2) nm,b=1.1235(2) nm,c=1.6860(3) nm,V=1.4479(5) nm3,μ(Mo Kα)=6.931 mm-1,Z=4,R1=0.0402 for 3236 reflections with Fo>2σ(Fo). The structure of compound 1 was formed by alternatively packing the inorganic layer of ZrGe3O8F2 and H...
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| 关 键 词： | 奇数 框架结构 显示 晶胞体积 模板分子 热稳定性 化合物 单晶衍射 |
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