Meeting experimental challenges to physics of network glasses: Assessing the role of sample homogeneity |
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Authors: | S Bhosle Ping Chen P Boolchand M Micoulaut |
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Institution: | a School of Electronic & Computing Systems, College of Engineering and Applied Science, University of Cincinnati, Cincinnati, OH 45221-0030, United Statesb Laboratoire de Physique Theorique de la Matiere Condensee, Universite Pierre et Marie Curie, Boite 121, 4 Place Jussieu, 75252 Paris Cedex 05, Francec Institut de Physique et de Chimie des Materiaux de Strasbourg, 23 rue du Loess, BP43, F-67034 Strasbourg Cedex 2, France |
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Abstract: | We introduce a Raman profiling method to track homogenization of GexSe100−x melts in real time, and show that 2 g melts reacted at 950 °C in high vacuum homogenize in 168 h on a scale of 10μm. Homogenization of melts is precursive to self-organization of glasses. In the present glasses, compositional variation of Raman active corner-sharing mode frequency of GeSe4 units, molar volumes, and the enthalpy of relaxation at Tg, reveal the rigidity (xc(1)=19.5(3)%) and the stress (xc(2)=26.0(3)%) transitions to be rather sharp (Δx<0.6%). These abrupt elastic phase transitions are in harmony with rigidity theory and have a direct bearing on the physics of glasses. |
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Keywords: | A Chalcogenide glasses D Self-organization E Raman scattering E Modulated DSC |
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