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Microwave-promoted one-pot conversion of alcohols to oximes using 1-methylimidazolium nitrate, [Hmim][NO3], as a green promoter and medium
Authors:Arsalan Mirjafari  Niloufar Mobarrez  James H Davis Jr  Jalil Noei
Institution:a Department of Chemistry, University of South Alabama, Mobile, Alabama 36688, USA
b Department of Chemical and biomolecular Engineering, University of South Alabama, Mobile, Alabama 36688, USA
c Department of Chemistry, Islamic Azad University, Mahshahr Branch, Mahshahr 63519, Iran
Abstract:A wide variety of oximes were prepared from different types of alcohols with hydroxylamine hydrochloride using 1-methylimidaziloum nitrate, Hmim]NO3], ionic liquid as a reaction medium and promoter under microwave irradiation. This protocol provides a one-pot oxime synthesis with high yields that is facile, eco-friendly and the ionic liquid can be recovered and reused.
Keywords:[Hmim][NO3]  Ionic liquids  Oxime  Microwave irradiation
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