Polystyrene-bound electron-deficient tin(IV) porphyrin: A new, highly efficient, robust and reusable catalyst for acetylation of alcohols and phenols with acetic anhydride |
| |
Authors: | Majid Moghadam Shahram Tangestaninejad Valiollah Mirkhani Iraj Mohammadpoor-Baltork Shadab Gharaati |
| |
Institution: | Department of Chemistry, Catalysis Division, University of Isfahan, Isfahan 81746-73441, Iran |
| |
Abstract: | In the present work, tetrakis(p-aminophenyl)porphyrinatotin(IV) trifluoromethanesulfonate, SnIV(TNH2PP)(OTf)2], supported on chloromethylated polystyrene was prepared and characterized by elemental analysis, FT IR and diffuse reflectance UV-Vis spectroscopic methods. This new heterogenized catalyst was used for acetylation of alcohols and phenols with acetic anhydride in short reaction times and high yields. The catalyst is of high reusability and stability in the acetylation reactions and was recovered several times without loss of its initial activity and catalyst leaching. |
| |
Keywords: | Alcohol Phenol Acetylation Polystyrene High-valent tin(IV) porphyrin |
本文献已被 ScienceDirect 等数据库收录! |
|