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Polystyrene-bound electron-deficient tin(IV) porphyrin: A new, highly efficient, robust and reusable catalyst for acetylation of alcohols and phenols with acetic anhydride
Authors:Majid Moghadam  Shahram Tangestaninejad  Valiollah Mirkhani  Iraj Mohammadpoor-Baltork  Shadab Gharaati
Institution:Department of Chemistry, Catalysis Division, University of Isfahan, Isfahan 81746-73441, Iran
Abstract:In the present work, tetrakis(p-aminophenyl)porphyrinatotin(IV) trifluoromethanesulfonate, SnIV(TNH2PP)(OTf)2], supported on chloromethylated polystyrene was prepared and characterized by elemental analysis, FT IR and diffuse reflectance UV-Vis spectroscopic methods. This new heterogenized catalyst was used for acetylation of alcohols and phenols with acetic anhydride in short reaction times and high yields. The catalyst is of high reusability and stability in the acetylation reactions and was recovered several times without loss of its initial activity and catalyst leaching.
Keywords:Alcohol  Phenol  Acetylation  Polystyrene  High-valent tin(IV) porphyrin
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