| N-乙酰基-3,3-二硝基氮杂环丁烷的合成 |
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| 引用本文： | 李洪珍,舒远杰,刘世俊,蒋青. N-乙酰基-3,3-二硝基氮杂环丁烷的合成[J]. 化学研究与应用, 2004, 16(3): 393-395 |
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| 作者姓名： | 李洪珍 舒远杰 刘世俊 蒋青 |
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| 作者单位： | 中国工程物理研究院化工材料研究所,四川,绵阳,621900;四川大学化学学院,四川,成都,610064 |
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| 基金项目： | 中国工程物理研究院基金 (NO .2 0 0 2 0 5 3 9)资助项目 |
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| 摘 要： | 多硝基氮杂环丁烷及其衍生物因其四元杂环所具有很高的环张力能，赋予这类化合物优良的爆轰性能，从而成为一类重要的高能量密度材料，其中1，3，3-三硝基氮杂环丁烷(TNAZ)成为最具有应用前景的含能材料之一。N-乙酰基-3，3-二硝基氮杂环丁烷(ADNAZ)，为白色或无色晶体，可溶于丙酮，二氯甲烷等有机溶剂。
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| 关 键 词： | 合成 N-乙酰基-3 3-二硝基氮杂环丁烷 含能材料 |
| 文章编号： | 1004-1656(2004)02-0393-03 |
| 修稿时间： | 2003-08-04 |
Synthesis of N-Acetyl-3,3-Dinitroazetidine |
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| LI Hong-zheng,SHU Yuan-jie,LIU Shi-jun,JIANG Qing. Synthesis of N-Acetyl-3,3-Dinitroazetidine[J]. Chemical Research and Application, 2004, 16(3): 393-395 |
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| Authors: | LI Hong-zheng SHU Yuan-jie LIU Shi-jun JIANG Qing |
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| Affiliation: | LI Hong-zheng~1,SHU Yuan-jie~1,LIU Shi-jun~1,JIANG Qing~2 |
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| Abstract: | A new high energetic density material,N-acetyl-3,3-dinitroazetidine(ADNAZ),was synthesized with advantages as low melting point,high density,insensitive to detonation on impact and forming a eutectic with TNAZ which can be shaped charge antitank weapons or be used energetic carrier for higher melting meaterial such as HMX and the like.ADNAZ was synthesized by a five-steps reaction,using nitromethane,paraformaldehyde and tert-butylamine etc.as starting materials,with overall yield of 42.8%.Some factors affecting yield of ADNAZ was also discussed.The structures of intermediates and ADNAZ were confirmed by IR,HNMR,CNMR and MS. |
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| Keywords: | synthesis N-acetyl-3 3-dinitroazetidme high energetic density material |
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