Exchange Interaction of a Novel Heterospin Polynuclear Complex Containing Transition Metals and Imino Nitroxide Radicals: {[(CuL)Ni(IM-2Py)_2](ClO_4)_2}_2·2H_2O |
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作者姓名: | 刘志亮 李立存 廖代正 姜宗慧 阎世平 |
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作者单位: | Department of Chemistry,Nankai University,Tianjin 300071,China,Department of Chemistry,Nankai University,Tianjin 300071,China,Department of Chemistry,Nankai University,Tianjin 300071,China,Department of Chemistry,Nankai University,Tianjin 300071,China State Key Laboratory of Coordination Chemistry,Nanjing University,Nanjing,Jiangsu 210093,China,Department of Chemistry,Nankai University,Tianjin 300071,China |
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基金项目: | ProjectsupportedbytheNationalNaturalScienceFoundationofChina (Nos .2 0 1710 2 5and 90 10 10 2 8) |
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摘 要: | IntroductionThemajorresearchaimsinthefieldofmolecularmag netismareontheonehandthedesignofmolecularassembliesthatexhibitaspontaneousmagnetizationandontheotherhandtherationalizationofmagnetostructuralcorrelation .1Polynuclearmacrocycliccomplexesandnitroxideradicalmetalliccomplexesaretwoactivefieldsofresearchfordesign ingandsynthesizingnewmagneticmaterials.2 6Polynuclearmacrocycliccomplexescontainingmul tiatomicbridgesuchasphenolateoxygen ,oxamidoandoxi amtogroupshavebeenconsiderablyinvestigated…
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