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Nanofluorides
Authors:Pavel P Fedorov  Anna A Luginina  Sergei V Kuznetsov  Vyacheslav V Osiko
Institution:A. M. Prokhorov General Physics Institute, Russian Academy of Sciences, 38 Vavilov Street, Moscow 119991, Russia
Abstract:The present review article covers major aspects of inorganic chemistry of nanofluorides, including methods of their synthesis (thermolysis of the precursors, co-precipitation from solutions, reversed micelle technique, hydro- and solvo-thermal techniques, sol–gel method, etc.), nanochemical effects (enhanced chemical activity, self-organization and self-assembly, non-classical mechanism of the single crystal growth, synthesis of non-equilibrium phases), targeted preparation of 1D, 2D, and 3D nanostructures, surface modification of the nanoparticles, fluoride nanocomposites (glass- and nano-ceramics) as well as applications of nanofluorides.
Keywords:Abbreviations: AFM  atomic force microscopy  BmimBF4  1-butyl-3-methylimidazolium tetrafluoroborate  BmimPF6  1-butyl-3-methylimidazolium hexafluorophosphate  CTAB  cetyl trimethyl ammonium bromide  DEG  diethyleneglycol  DPA  dipicolinate  DI  deionized water  EDTA  ethylenediaminetetraacetic acid  HEEDA  n-(2-hydroxyethyl) ethylenediamine  HEDP  1-hydroxyethane-1  1-diphosphonic acid  HTSC  high temperature superconductors  Igepal  polyoxoethylene nonyl phenol  ILs  ionic liquid solvents  NIR  near-infrared range  NPAs  nanoparticle associates  OA  oleic acid  ODE  l-octadecene" target="_blank">l-octadecene  OM  oleylamine  PAA  polyacrylic acid  PEI  polyethyleneimine  PEG  polyethylene glycol  PS  polystyrene  QC  quantum cutting  QDs  quantum dots  STEM  scanning and transmission electron microscopy  TEOS  tetraethyl orthosilicate  THF  tetrahydrofuran  TOP  trioctylphosphine  TOPO  trioctylphosphine oxide  UCNPs  upconverting nanoparticles
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